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Siriwardana, Amal I, Crossley, Ian R, Torriero, Angel A J, Burgar, Iko M, Dunlop, Noel F, Bond, Alan M, Deacon, Glen B and MacFarlane, Douglas R (2008) Methimazole-Based Ionic Liquids. The Journal of Organic Chemistry, 73 (12). pp. 4676-4679. ISSN 0022-3263
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Official URL: http://dx.doi.org/10.1021/jo702511v
Abstract
The alkylation reaction of 2-mercapto-1-methylimidazole 1a with iodoethane and chlorobutane produced S-alkylmethimazole halides 2a and 2b which were subjected to anion metathesis with two different metal salts (MA) to afford methimazole-based room-temperature ionic liquids 3a, 3b, and 3c in 82%, 85%, and 87% yields, respectively. S-Alkylation giving 2a and 2b suggests that methimazole reacts through the thione tautomer.
Item Type: | Article |
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Additional Information: | 'second author' two other experimentalists. IMB, NFD, AMB, GBD, DRM all 'management team' |
Schools and Departments: | School of Life Sciences > Chemistry |
Depositing User: | Ian Crossley |
Date Deposited: | 06 Feb 2012 21:08 |
Last Modified: | 24 Jul 2013 11:34 |
URI: | http://sro.sussex.ac.uk/id/eprint/29748 |