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Oakley, Sarah H, Coles, Martyn P and Hitchcock, Peter B (2003) Structural and Catalytic Properties of Bis(guanidine)copper(I) Halides. Inorganic Chemistry, 42 (10). 3154 - 3156. ISSN 0020-1669
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Official URL: http://pubs3.acs.org/acs/journals/doilookup?in_doi...
Abstract
The neutral, bicyclic guanidine 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine (hppH) coordinates to Cu(I) halides via the imine nitrogen, and the complexes are stabilized by intramolecular NX interactions (X = Cl, Br) or are partially dissociated (X = I) in the solid state; in all cases, fluxional behavior is observed in solution. Selected complexes have been tested as catalysts for the polymerization of methyl methacrylate.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Depositing User: | Martyn Coles |
Date Deposited: | 06 Feb 2012 20:55 |
Last Modified: | 19 Mar 2013 14:04 |
URI: | http://sro.sussex.ac.uk/id/eprint/28734 |