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Activation and reduction of diethyl ether by low valent uranium: formation of the trimetallic, mixed valence uranium oxo species [U(CpRR)(µ-I)2]3(µ3-O) (CpRR = C5Me5, C5Me4H, C5H4SiMe3)

journal contribution
posted on 2023-06-08, 08:13 authored by Christopher P Larch, Geoff Cloke, Peter B Hitchcock
The reaction of UI3 and KCpRR' (CpRR' = pentamethylcyclopentadienyl, trimethylsilylcyclopentadienyl or tetramethylcyclopentadienyl) in diethyl ether results in the two-electron reduction of the solvent to form trimetallic, mixed valence uranium oxo species.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

1364-548X

Publisher

RSC Publishing

Issue

1

Volume

44

Page range

82-84

Pages

3.0

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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