The sulfinyl moiety in Lewis base-promoted allylations

Fulton, J Robin, Kamara, Lamin M, Morton, Simon C and Rowlands, Gareth J (2009) The sulfinyl moiety in Lewis base-promoted allylations. Tetrahedron, 65 (45). pp. 9134-9141. ISSN 0040-4020

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By employing Senanayake's oxathiazolidine-2-oxide reagent, a collection of sulfinamides was prepared and provided the first examples of sulfinamides promoting the allylation of benzaldehyde and N-benzoylhydrazones with allyltrichlorosilane. The optimum sulfinamide-derived Lewis base promoter displays comparable activity to the best sulfinyl-based Lewis bases reported. The use of bis-sulfoxides is also discussed.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Robin Fulton
Date Deposited: 06 Feb 2012 20:50
Last Modified: 28 Mar 2012 13:36
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