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Fulton, J Robin, Kamara, Lamin M, Morton, Simon C and Rowlands, Gareth J (2009) The sulfinyl moiety in Lewis base-promoted allylations. Tetrahedron, 65 (45). pp. 9134-9141. ISSN 0040-4020
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Official URL: http://dx.doi.org/10.1016/j.tet.2009.09.042
Abstract
By employing Senanayake's oxathiazolidine-2-oxide reagent, a collection of sulfinamides was prepared and provided the first examples of sulfinamides promoting the allylation of benzaldehyde and N-benzoylhydrazones with allyltrichlorosilane. The optimum sulfinamide-derived Lewis base promoter displays comparable activity to the best sulfinyl-based Lewis bases reported. The use of bis-sulfoxides is also discussed.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Depositing User: | Robin Fulton |
Date Deposited: | 06 Feb 2012 20:50 |
Last Modified: | 28 Mar 2012 13:36 |
URI: | http://sro.sussex.ac.uk/id/eprint/28406 |