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An improved synthesis of bis(1, 3-di-N-tert-buylimidazol-2-ylidene)palladium(0) and its use in C-C and C-N coupling reactions

journal contribution
posted on 2023-06-08, 07:51 authored by Stephen Caddick, Geoff Cloke, Guy K B Clentsmith, Peter B Hitchcock, Darren McKerrecher, Lisa R Titcomb, Meredith R V Williams
A new, improved synthesis of [Pd{CN(tBu)(CH)2N(tBu)}2] (1) and its use as a catalyst in coupling reactions, including aminations, is presented. An interesting side product formed in the synthesis of 1, [Pd(¿3-C4H7){(CN(tBu)(CH) 2N(tBu)}Cl] (2), is also discussed. © 2001 Elsevier Science B.V.

History

Publication status

  • Published

Journal

Journal of Organometallic Chemistry

ISSN

0022328X

Volume

617-61

Page range

635-639

Pages

5.0

Department affiliated with

  • Chemistry Publications

Notes

Other internal authors: Lisa R. Titcomb, Meredith R.V Williams

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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