University of Sussex
Browse

File(s) not publicly available

Synthesis of the Ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}] (Ru-B)8 and [Ru(CO)(CNR){B(mt)3}] (Ru-B)8 (mt = methimazolyl, R = tBu, C6H3Me2-2,6, C6H2Me3-2,4,6)

journal contribution
posted on 2023-06-08, 07:13 authored by Ian CrossleyIan Crossley, Mark R St-J Foreman, Anthony F Hill, Gareth R Owen, Andrew J P White, David J Williams, Anthony C Willis
The reaction of [Ru(CHCH2)Cl(CS)(PPh3)2] with Na[HB(mt)3] (mt = methimazolyl) provides the ruthenaboratrane [Ru(CS)(PPh3){B(mt)3}]. The reaction of [Ru(CO)(PPh3){B(mt)3}] with CO to provide [Ru(CO)2{B(mt)3}] is reversible, while the phosphine-free ruthenaboratranes [Ru(CO)(CNR){B(mt)3}] (R = tBu, C6H3Me2-2,6, C6H2Me3-2,4,6) form irreversibly upon addition of isonitriles (CNR) to [Ru(CO)(PPh3){B(mt)3}]. The crystal structures of the ruthenaboratranes [Ru(CS)(PPh3){B(mt)3}], [Ru(CO)(CNtBu)({B(mt)3}], and [Ru(CO)(CNC6H2Me3-2,4,6){B(mt)3}] are reported.

History

Publication status

  • Published

Journal

Organometallics

ISSN

0276-7333

Publisher

American Chemical Society

Volume

27

Page range

381-386

Department affiliated with

  • Chemistry Publications

Notes

Equal contributor with two other experimentalists. Corresponding author (AFH) was group PI, other authors were crystallographers

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

Usage metrics

    University of Sussex (Publications)

    Categories

    No categories selected

    Exports

    RefWorks
    BibTeX
    Ref. manager
    Endnote
    DataCite
    NLM
    DC