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1-Triphenylstannyl-2,4,5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3But3: Preparation, X-ray crystal structure, theoretical studies and solution fluxional behaviour
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posted on 2023-06-08, 07:00 authored by Geoff Cloke, Peter B Hitchcock, John F Nixon, D James Wilson, Laszlo Nyulászi, Tamas KarpatiThe 1-triphenylstannyl-2, 4, 5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3Bu3t, which has been synthesised from Ph3SnCl and KP2C3Bu3t, has been fully structurally characterised in the solid state but in solution undergoes ready intra-molecular shifts of the Ph3Sn-group around the 1,3-diphospholyl ring. Theoretical calculations concerning both the structure and the dynamic process are presented and discussed.
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Publication status
- Published
Journal
Journal of Organometallic ChemistryISSN
0022328XPublisher
ElsevierExternal DOI
Issue
17Volume
690Page range
3983 - 3989Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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