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1-Triphenylstannyl-2,4,5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3But3: Preparation, X-ray crystal structure, theoretical studies and solution fluxional behaviour

journal contribution
posted on 2023-06-08, 07:00 authored by Geoff Cloke, Peter B Hitchcock, John F Nixon, D James Wilson, Laszlo Nyulászi, Tamas Karpati
The 1-triphenylstannyl-2, 4, 5-tritertiarybutyl-1,3-diphosphole, Ph3SnP2C3Bu3t, which has been synthesised from Ph3SnCl and KP2C3Bu3t, has been fully structurally characterised in the solid state but in solution undergoes ready intra-molecular shifts of the Ph3Sn-group around the 1,3-diphospholyl ring. Theoretical calculations concerning both the structure and the dynamic process are presented and discussed.

History

Publication status

  • Published

Journal

Journal of Organometallic Chemistry

ISSN

0022328X

Publisher

Elsevier

Issue

17

Volume

690

Page range

3983 - 3989

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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