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Oh, Kyung Soo, Cheshire, David and Parsons, Philip J (2005) Studies towards the synthesis of rapamycin: Regiocontrol in the addition of carbanions to enantiomerically pure epoxides and the formation of a highly substituted tetrahydrofuran. Synlett, - (10). pp. 1630-1632. ISSN 09365214
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Official URL: http://dx.doi.org/10.1055/s-2005-869868
Abstract
Reaction of trimethylaluminium, dimethyllithium cuprate and lithium tetramethylaluminate with the homochiral epoxide 8 has been studied. Intermolecular epoxide ring-opening was observed with dimethyllithium cuprate and lithium tetramethylaluminate, but acetal ring-opening followed by intramolecular epoxide ring-opening was observed with trimethylaluminium.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Depositing User: | Philip Parsons |
Date Deposited: | 06 Feb 2012 20:19 |
Last Modified: | 27 Mar 2012 10:59 |
URI: | http://sro.sussex.ac.uk/id/eprint/25396 |