University of Sussex
Browse

File(s) not publicly available

Tris[\{dimethylamido)dimethylsilyl\}magnesium iodide. A Grignard Reagent without a carbon-magnesium bond?

journal contribution
posted on 2023-06-08, 05:11 authored by Colin Eaborn, Adam Farook, Peter Hitchcock, David J Smith
Reaction of (Me2NMe2Si)3CI with Mg gives the Grignard reagent (Me2NMe2Si)3CMgI, in which all three N atoms are coordinated to Mg and there is a planar carbanionic center, suggesting the absence of Mg bonding.

History

Publication status

  • Published

Journal

Organometallics

Publisher

Organometallics

Volume

16

Page range

503-504

ISBN

0276-7333

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

Usage metrics

    University of Sussex (Publications)

    Categories

    No categories selected

    Exports

    RefWorks
    BibTeX
    Ref. manager
    Endnote
    DataCite
    NLM
    DC