Synthetic, structural and theoretical studies on new aromatic 1,2,4- azadiphosphole ring systems: Crystal and molecular structure of P2C2Bu(t)2NPh

Cloke, F Geoffrey N, Hitchcock, Peter B, Nixon, John F, Wilson, D James, Tabellion, Frank, Fischbeck, Uwe, Preuss, Fritz and Regitz, Manfred (1999) Synthetic, structural and theoretical studies on new aromatic 1,2,4- azadiphosphole ring systems: Crystal and molecular structure of P2C2Bu(t)2NPh. Chemical Communications, - (23). pp. 2363-2364. ISSN 13597345

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Abstract

Two different synthetic routes to the new aromatic 1,2,4-aza-diphosphole ring system P2C2Bu(t)2NR (R = Pr(i), Pr, Ph, MeC6H4, Bu(t)CH2 and cyclohexyl) are presented and the planar structure of P2C2Bu(t)2NPh, established by a single crystal X-ray diffraction study, is in good agreement with theoretical calculations at the B3LYP/6-311G* level on the parent P2C2H2NH ring.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Geoff Cloke
Date Deposited: 06 Feb 2012 20:07
Last Modified: 26 Mar 2012 15:54
URI: http://sro.sussex.ac.uk/id/eprint/24115
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