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Bates, Vanessa M E, Clentsmith, Guy K B, Cloke, F Geoffrey N, Green, Jennifer C and Jenkin, Huw D Ll (2000) Theoretical investigation of the pathway for reductive cleavage of dinitrogen by a vanadium diamidoamine complex. Chemical Communications, - (11). pp. 927-928. ISSN 13597345
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Official URL: http://dx.doi.org/10.1039/B002534H
Abstract
Density functional calculations show that [HN(CH2CH2NH)2V] will bind N2 in a sideways fashion; further reaction with another molecule of [HN(CH2CH2NH)2V] leads to reductive cleavage of the N2 moiety to form a bridged nitrido dimer, [HN(CH2CH2NH)2V(µ-N)]2; this study provides a model for the formation of [RN(CH2CH2NR)2V(µ-N)]2 (R = SiMe3) by reduction of [RN(CH2CH2NR)2V(µ-Cl)]2 under an N2 atmosphere.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Depositing User: | Geoff Cloke |
Date Deposited: | 06 Feb 2012 20:04 |
Last Modified: | 26 Mar 2012 13:58 |
URI: | http://sro.sussex.ac.uk/id/eprint/23884 |