File(s) not publicly available
Theoretical investigation of the pathway for reductive cleavage of dinitrogen by a vanadium diamidoamine complex
journal contribution
posted on 2023-06-08, 04:52 authored by Vanessa M E Bates, Guy K B Clentsmith, Geoff Cloke, Jennifer C Green, Huw D Ll JenkinDensity functional calculations show that [HN(CH2CH2NH)2V] will bind N2 in a sideways fashion; further reaction with another molecule of [HN(CH2CH2NH)2V] leads to reductive cleavage of the N2 moiety to form a bridged nitrido dimer, [HN(CH2CH2NH)2V(µ-N)]2; this study provides a model for the formation of [RN(CH2CH2NR)2V(µ-N)]2 (R = SiMe3) by reduction of [RN(CH2CH2NR)2V(µ-Cl)]2 under an N2 atmosphere.
History
Publication status
- Published
Journal
Chemical CommunicationsISSN
13597345External DOI
Issue
11Volume
-Page range
927-928Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
Categories
No categories selectedKeywords
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC