Titanium Complexes Incorporating Bicyclic Guanidinate Ligands. Structure of a Novel Titanium-Aluminium Complex

Coles, Martyn p and Hitchcock, Peter B (2001) Titanium Complexes Incorporating Bicyclic Guanidinate Ligands. Structure of a Novel Titanium-Aluminium Complex. Journal of the Chemical Society, Dalton Transactions, - (8). 1169 - 1171. ISSN 1472-7773

Full text not available from this repository.

Abstract

Synthetic routes to titanium complexes incorporating the bicyclic guanidinate, 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate, [hpp]¿, are described; the first example of a chelating coordination mode for the [hpp]¿ anion and the trimetallic complex [Me2Al(hpp)2TiClAlMe3] containing [hpp]¿ ligands that chelate to titanium and, in addition, bridge to an AlMe2 unit via nitrogen are reported.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Martyn Coles
Date Deposited: 06 Feb 2012 19:59
Last Modified: 19 Mar 2013 13:59
URI: http://sro.sussex.ac.uk/id/eprint/23445
📧 Request an update