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Titanium Complexes Incorporating Bicyclic Guanidinate Ligands. Structure of a Novel Titanium-Aluminium Complex

journal contribution
posted on 2023-06-08, 00:52 authored by Martyn p Coles, Peter B Hitchcock
Synthetic routes to titanium complexes incorporating the bicyclic guanidinate, 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate, [hpp]¿, are described; the first example of a chelating coordination mode for the [hpp]¿ anion and the trimetallic complex [Me2Al(hpp)2TiClAlMe3] containing [hpp]¿ ligands that chelate to titanium and, in addition, bridge to an AlMe2 unit via nitrogen are reported.

History

Publication status

  • Published

Journal

Journal of the Chemical Society, Dalton Transactions

ISSN

1472-7773

Publisher

RSC Publishing

Issue

8

Volume

-

Page range

1169 - 1171

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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