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Titanium Complexes Incorporating Bicyclic Guanidinate Ligands. Structure of a Novel Titanium-Aluminium Complex
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posted on 2023-06-08, 00:52 authored by Martyn p Coles, Peter B HitchcockSynthetic routes to titanium complexes incorporating the bicyclic guanidinate, 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate, [hpp]¿, are described; the first example of a chelating coordination mode for the [hpp]¿ anion and the trimetallic complex [Me2Al(hpp)2TiClAlMe3] containing [hpp]¿ ligands that chelate to titanium and, in addition, bridge to an AlMe2 unit via nitrogen are reported.
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Publication status
- Published
Journal
Journal of the Chemical Society, Dalton TransactionsISSN
1472-7773Publisher
RSC PublishingExternal DOI
Issue
8Volume
-Page range
1169 - 1171Department affiliated with
- Chemistry Publications
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- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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