Fryzuk, Michael D, Jafarpour, Lalah, Kerton, Francesca M, Love, Jason B and Rettig, Steven J (2000) Dinuclear p Complexes of Yttrium and Lutetium with Sandwiched Naphthalene and Anthracene Ligands: Evidence for Rapid Intramolecular Inter-Ring Rearrangements. Angewandte Chemie International Edition, 39:04:. p. 767. ISSN 1433-7851

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Abstract

Unusual, rapid fluxional behavior is exhibited by polyarene complexes of yttrium(III) and lutetium(III), which were obtained as intensely colored compounds by the reaction of [{(`P2N2')Ln}2(μ-Cl)2] with naphthalene or anthracene in the presence of KC8. Inter-ring migration of the Ln(`P2N2') unit is proposed on the basis of NMR spectroscopic data. The picture shows the structure of an yttrium naphthalene complex. `P2N2'=PhP(CH2SiMe2NSiMe2CH2)2PPh.

Item Type:	Article
Schools and Departments:	School of Life Sciences > Chemistry
Depositing User:	EPrints Services
Date Deposited:	06 Feb 2012 19:57
Last Modified:	30 Nov 2012 17:05
URI:	http://sro.sussex.ac.uk/id/eprint/23181

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