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Dinuclear p Complexes of Yttrium and Lutetium with Sandwiched Naphthalene and Anthracene Ligands: Evidence for Rapid Intramolecular Inter-Ring Rearrangements
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posted on 2023-06-08, 00:41 authored by Michael D Fryzuk, Lalah Jafarpour, Francesca M Kerton, Jason B Love, Steven J RettigUnusual, rapid fluxional behavior is exhibited by polyarene complexes of yttrium(III) and lutetium(III), which were obtained as intensely colored compounds by the reaction of [{(`P2N2')Ln}2(µ-Cl)2] with naphthalene or anthracene in the presence of KC8. Inter-ring migration of the Ln(`P2N2') unit is proposed on the basis of NMR spectroscopic data. The picture shows the structure of an yttrium naphthalene complex. `P2N2'=PhP(CH2SiMe2NSiMe2CH2)2PPh.
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- Published
Journal
Angewandte Chemie International EditionISSN
1433-7851Publisher
John Wiley & SonsVolume
39:04:Page range
767ISBN
1433-7851Department affiliated with
- Chemistry Publications
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- No
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- Yes
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2012-02-06Usage metrics
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