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Studies on Pd/imidazolium salt protocols for aminations of aryl bromides and iodides using lithium hexamethyldisilazide (LHMDS)

journal contribution
posted on 2023-06-08, 00:31 authored by Israel Conesa Lerma, Mark J Cawley, Geoff Cloke, Katherine Arentsen, James S Scott, Stuart E Pearson, John Hayler, Stephen Caddick
The reactions of a range of secondary amines with aryl bromides and iodides have been performed using an in situ protocol involving palladium and imidazolium salts. Many of these reactions proceed at room temperature, providing a mild protocol for aminations of aryl iodides and bromides. Key to the success of this procedure is the use of lithium hexamethyldisilazide (LHMDS) as base.

History

Publication status

  • Published

Journal

Journal of Organometallic Chemistry

ISSN

0022328X

Issue

24

Volume

690

Page range

5841-5848

Department affiliated with

  • Chemistry Publications

Notes

Pearson, S E. Hayler, J. Caddick, S.

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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