Open-cage fullerene derivatives with 15-membered-ring orifices

Vougioukalakis, Georgios C, Prassides, Kosmas, Campanera, Josep M, Heggie, Malcolm I and Orfanopoulos, Michael (2004) Open-cage fullerene derivatives with 15-membered-ring orifices. Journal of Organic Chemistry, 69 (13). pp. 4524-4526. ISSN 00223263

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The addition reaction of the N-MEM-ketolactam derivative of [60]fullerene with phenyl, p-Br-phenyl, and p-MeO-phenyl hydrazines proceeds regioselectively, affording three open-cage fullerene derivatives bearing a 15-membered-ring orifice on the fullerene cage. Both experimental data and theoretical calculations were utilized for the structure determination of the new [60]fullerene adducts.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Josep CampaneraAlsina
Date Deposited: 06 Feb 2012 19:50
Last Modified: 23 Mar 2012 17:26
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