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Metal Complexes of Guanidine-Substituted Alkyl Ligands: An Unsolvated Monomeric Two-Coordinate Organolithium
journal contribution
posted on 2023-06-07, 23:33 authored by Martyn P Coles, Sebnem E. Sozerli, J David Smith, Peter B HitchcockSingle-crystal X-ray diffraction of MC(SiMe3)2(SiMe2hpp) (M = Li, K; hppH = 1,3,4,6,7,8,-hexahydro-2H-pyrimido[1,2-a]pyrimidine) showed nonsolvated organometallic compounds in which the iminonitrogen of the guanidine forms strong intramolecular bonds to generate six-membered metallacycles.
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Publication status
- Published
Journal
OrganometallicsISSN
02767333External DOI
Issue
27Volume
26Page range
6691-6693Department affiliated with
- Chemistry Publications
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- No
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- Yes
Legacy Posted Date
2012-02-06Usage metrics
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