Cloke, F Geoffrey N, Hitchcock, Peter B, Hunnable, Philip, Nixon, John F, Nyulászi, Laszlo, Niecke, Edgar and Thelen, Vera (1998) The first delocalized phosphole containing a planar tricoordinate phosphorus atom: 1-[bis(trimethylsilyl)methyl]-3,5-bis(trimethylsilyl)-1,2,4-triphosphole. Angewandte Chemie International Edition, 37 (8). pp. 1083-1086. ISSN 1433-7851
Full text not available from this repository.Abstract
The sterically demanding groups on the tricoordinate phosphorus atom, the pi-electron acceptors substituted on the ring, and the dicoordinate phosphorus atoms within the ring are the most significant factors contributing to the planarity and aromaticity of the 1,2,4-triphosphole ring in 1. The Bird aromaticity index for 1 shows that it has the most pronounced aromatic character of all known phospholes.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Depositing User: | Geoff Cloke |
Date Deposited: | 06 Feb 2012 19:29 |
Last Modified: | 07 Jun 2012 15:16 |
URI: | http://sro.sussex.ac.uk/id/eprint/20790 |