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The first mononuclear h8 -coordinated pentalene complex: synthesis and molecular structure of [Ta\{ h8 -C8H4(siMe3)2-14\}CI3]
journal contribution
posted on 2023-06-07, 22:58 authored by Qasim A Abbasali, Geoff Cloke, Peter B Hitchcock, Stephen C P JosephTreatment of [TaCl2Me3] with Li2(cot¿) (cot¿ = 1,4-bis(trimethylsilyl)cyclooctatetraene] affords [Ta(¿-cot¿)Me3], which reacts with [NHPri2Et]Cl in dichloromethane to yield the complex [Ta{¿8-C8H4(SiMe3) 2-1,4}Cl3]; X-ray crystallography shows the latter to contain a pentalene ligand bound through all eight carbons to a single tantalum centre.
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Publication status
- Published
Journal
Chemical CommunicationsISSN
13597345Publisher
Chemical CommunicationsExternal DOI
Issue
16Volume
-Page range
1541 - 1542ISBN
1359-7345Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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