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Beta-Diiminato Ligand (L) Transformations in Reactions of KL with PI3 and I2 [L = {N(C6H3Pr12-2,6)C(H)}2CPh]

journal contribution
posted on 2023-06-07, 22:57 authored by Michael F Lappert, Peter B Hitchcock, Gang Li, Andrey V Protchenko
The reaction of the potassium ß-diiminate KL (L = [{N(Ar)C(H)}2CPh]-; Ar = C6H3Pri2-2,6) with PI3 unexpectedly produced a phosphenium salt of the intermolecularly C,C-coupled ligand [P(I){N(Ar)CH}2C(C6H4-4)C(Ph)(CH[double bond, length as m-dash]NAr)2]+[I3]-, while an intramolecularly N,N-coupled salt [N[upper bond 1 start](Ar)C(H)C(Ph)C(H)N[upper bond 1 end](Ar)]+[I5]- was isolated from KL + I2.

History

Publication status

  • Published

Journal

Chemical Communications

ISSN

1359-7345

Publisher

Royal Society of Chemistry

External DOI

Issue

8

Page range

846-848

Pages

3.0

Department affiliated with

  • Chemistry Publications

Notes

Remarkably novel reactions of the nitrenium iodide [N(Ar)=C(H)-C(Ph)=C(H)-N(Ar]I complex as a plausible intermediates. MFL directed the work and is principal and corresponding author.

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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