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Synthesis and reactivity of the phospha-Grignard reagent Mg(P{SiMe 3}2)Br(thf)

journal contribution
posted on 2023-06-07, 21:43 authored by Benjamin M Day, Martyn P Coles
The novel phospha-Grignard reagent Mg(PR2')X(thf) [R' = SiMe3, X = Br (1)/Me (1')] was synthesized and structurally characterized as the phosphide-bridged dimer [1](2). The potential for this compound to behave as a redox-friendly phosphide transfer reagent was probed by its reaction with group 4 metallocene compounds Cp2MCl2 (M = Ti, Zr),resulting in phosphide transfer to zirconium, but reduction of the titanium centre to Ti-III.

History

Publication status

  • Published

Journal

European Journal of Inorganic Chemistry

ISSN

1434-1948

Issue

34

Page range

5471-5477

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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