Cloke, F Geoffrey N, Hitchcock, Peter B, Nixon, John F and Wilson, D James (2000) First catalytic dihydroamination of a phosphaalkyne. Crystal and molecular structure of trans-[PdCl2{P(Pr(i)NH)2CH2Bu(t)}2]. Chemical Communications, - (23). pp. 2387-2388. ISSN 13597345

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Abstract

Treatment of a dichloromethane solution of Bu(t)CP, containing a catalytic amount of TiCl4, with an excess of the primary amines RNH2 (R = Pr(i), Bu(t)) quantitatively affords the corresponding bis-dialkylaminophosphine P(Bu(t)NH)2-CH2Bu(t). P(Pr(i)NH)2CH2Bu(t) is structurally characterised by a single crystal X-ray diffraction study of its bis-trans-PdCl2 complex.

Item Type:	Article
Schools and Departments:	School of Life Sciences > Chemistry
Depositing User:	Geoff Cloke
Date Deposited:	06 Feb 2012 18:53
Last Modified:	19 Mar 2012 17:07
URI:	http://sro.sussex.ac.uk/id/eprint/18782

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