(Phosphacyclopentadienyl)indium(I) derivatives: Synthesis and X-ray crystal structure of [In(¿5-P3C2But2)]

Callaghan, Charlotte, Clentsmith, Guy K B, Cloke, F Geoffrey N, Hitchcock, Peter B, Nixon, John F and Vickers, D M (1999) (Phosphacyclopentadienyl)indium(I) derivatives: Synthesis and X-ray crystal structure of [In(¿5-P3C2But2)]. Organometallics, 18 (4). ISSN 02767333

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Co-condensation of indium vapor and tert-butylphosphaethyne at 77 K yields two new, volatile In-(1) complexes: [In(¿5-P3C2But2)] (1) and [In(¿5-P2C3But3)] (2). A single-crystal X-ray diffraction experiment on 1 reveals a discrete molecular structure, involving half-sandwich coordination of the P3C2But2 ring around the indium center. 1 may be independently prepared by treating InI with the newly synthesized, base-free ligand salt K(P3C2But2).

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Geoff Cloke
Date Deposited: 06 Feb 2012 18:52
Last Modified: 19 Mar 2012 16:56
URI: http://sro.sussex.ac.uk/id/eprint/18733
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