Cloke, F Geoffrey N, Hitchcock, Peter B, Nixon, John F and Wilson, D James (2000) Remarkable Transformation of 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene into the 2,4,5-Tri-tert -butyl-1,3-diphosphacyclopentadienide Anion. Organometallics, 19 (3). pp. 219-220. ISSN 02767333

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Abstract

In an unprecedented reaction, the reduction of 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene over a potassium mirror in toluene resulted in the abstraction of P3- and generation of the 2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienide anion, P2C3Bu3t- (3). The potassium salt of this anion was characterized by an X-ray crystallographic study.

Item Type:	Article
Schools and Departments:	School of Life Sciences > Chemistry
Depositing User:	Geoff Cloke
Date Deposited:	06 Feb 2012 18:50
Last Modified:	19 Mar 2012 16:28
URI:	http://sro.sussex.ac.uk/id/eprint/18584

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