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Remarkable Transformation of 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene into the 2,4,5-Tri-tert -butyl-1,3-diphosphacyclopentadienide Anion
journal contribution
posted on 2023-06-07, 21:32 authored by Geoff Cloke, Peter B Hitchcock, John F Nixon, D James WilsonIn an unprecedented reaction, the reduction of 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene over a potassium mirror in toluene resulted in the abstraction of P3- and generation of the 2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienide anion, P2C3Bu3t- (3). The potassium salt of this anion was characterized by an X-ray crystallographic study.
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Publication status
- Published
Journal
OrganometallicsISSN
02767333Issue
3Volume
19Page range
219-220Department affiliated with
- Chemistry Publications
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- No
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- Yes
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2012-02-06Usage metrics
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