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Remarkable Transformation of 2,4,6-Tri-tert-butyl-1,3,5-triphosphabenzene into the 2,4,5-Tri-tert -butyl-1,3-diphosphacyclopentadienide Anion

journal contribution
posted on 2023-06-07, 21:32 authored by Geoff Cloke, Peter B Hitchcock, John F Nixon, D James Wilson
In an unprecedented reaction, the reduction of 2,4,6-tri-tert-butyl-1,3,5-triphosphabenzene over a potassium mirror in toluene resulted in the abstraction of P3- and generation of the 2,4,5-tri-tert-butyl-1,3-diphosphacyclopentadienide anion, P2C3Bu3t- (3). The potassium salt of this anion was characterized by an X-ray crystallographic study.

History

Publication status

  • Published

Journal

Organometallics

ISSN

02767333

Issue

3

Volume

19

Page range

219-220

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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