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A New Bonding Mode for the Bicyclic Guanidinate, [hpp]-, in the Tetrametallic Yttrium Oxide Cluster, Y4(hpp)8Cl2(m4-O)

journal contribution
posted on 2023-06-07, 21:15 authored by Martyn P Coles, Peter B Hitchcock
Oxygen incorporation in the product of the reaction between YCl3 and the lithium salt of 1,3,4,6,7,8-hexahydro-2Hpyrimido[1,2-a]pyrimidine (hppH) afforded the tetrametallic cluster Y4(hpp)8Cl2(¿4-O), in which four of the guanidinate anions are involved in a previously unreported ¿,¿2,¿2-bridging mode between two metal centres.

History

Publication status

  • Published

Journal

Inorganica Chimica Acta

ISSN

0020-1693

Issue

14

Volume

357

Page range

4330 - 4334

Department affiliated with

  • Chemistry Publications

Full text available

  • No

Peer reviewed?

  • Yes

Legacy Posted Date

2012-02-06

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