A Lewis-basic, Dionio-Substituted Phosphane

Coles, Martyn P and Hitchcock, Peter B (2007) A Lewis-basic, Dionio-Substituted Phosphane. Chemical Communications, - (48). pp. 5229-5231. ISSN 13597345

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Bis{guanidine} H2C{hpp}2[hppH = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine] reacts with PPhCl2 to generate the dionio-substituted phosphane, [H2C{hpp}2PPh]2+[Cl]2 which, despite the formally dicationic phosphorus centre, forms an unprecedented coordination compound with platinum.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Martyn Coles
Date Deposited: 06 Feb 2012 18:37
Last Modified: 19 Mar 2012 12:00
URI: http://sro.sussex.ac.uk/id/eprint/17432
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