Goryunkov, A A, Markov, V Y, Boltalina, O V, Zemva, B, Abdul-Sada, A K and Taylor, R (2001) Reaction of silver(I) and (II) fluorides with C-60: thermodynamic control over fluorination level. Journal of Fluorine Chemistry, 112 (2). pp. 191-196. ISSN 0022-1139

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Abstract

Silver(I) fluoride is shown to be a weak fluorinating agent (FA) for C-60 and gives mainly C60F18. Fluorination with silver(II) fluoride yields C60F44, a new compound, as the predominant product (> 80% in the crude). Fluorination degree of fullerenes in reaction with binary metal fluorides is found to be mainly thermodynamically controlled. The correlation between the level of C-60 fluorination and oxidising fluorinating strength of the metal fluorides used for fluorofullerene preparations is discussed, permitting development of a self-consistent quantitative scale for inorganic FAs.

Item Type:	Article
Schools and Departments:	School of Life Sciences > Chemistry
Depositing User:	Alaa Abdul-Sada
Date Deposited:	06 Feb 2012 18:35
Last Modified:	01 May 2012 15:00
URI:	http://sro.sussex.ac.uk/id/eprint/17264

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