Novel formation of a phenylated isoquinolino[3 ',4 ': 1,2][60]fullerene

Abdul-Sada, Ala'a, Avent, Anthony G, Birkett, P R, Darwish, Adam D, Kroto, Harold W, Taylor, Roger, Walton, David R M and Woodhouse, Oliver B (1998) Novel formation of a phenylated isoquinolino[3 ',4 ': 1,2][60]fullerene. Chemical Communications (3). pp. 307-308. ISSN 1359-7345

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Reaction of C60Ph5Cl With cyanogen bromide results in replacement of the chlorine by BrCN and ring closure between the addend and an adjacent phenyl ring, giving a 1-bromoisoquinoline derivative of [60]fullerene; this readily undergoes nucleophilic replacement of Br by OH to give the corresponding 1-isoquinolone derivative.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Depositing User: Alaa Abdul-Sada
Date Deposited: 06 Feb 2012 18:32
Last Modified: 12 Jun 2012 12:24
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