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Hanson, James R, Hitchcock, Peter B and Kiran, Ismail (1999) Neighbouring group participation in the methanolysis of a vicinal diepoxide. Journal of Chemical Research, Synopses, 6. 356 - 357. ISSN 0308-2342
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Official URL: http://dx.doi.org/10.1039/A901346F
Abstract
The tetracyanoethylene catalysed methanolysis of 17β-acetoxy-4β,5β:6α,7α-diepoxyandrostane afforded 17β-acetoxy-4α,7α-oxido-5β-hydroxy-6β-methoxyandrostane in which the methanolysis product of the 6α,7α-epoxide has participated in the cleavage of the 4β,5β-epoxide; the reaction is modified however by an adjacent 3β-hydroxy group.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Depositing User: | James Hanson |
Date Deposited: | 06 Feb 2012 18:30 |
Last Modified: | 14 Sep 2012 12:54 |
URI: | http://sro.sussex.ac.uk/id/eprint/16830 |