Crossley, Ian R, Hill, Anthony F and Willis, Anthony C (2008) Retention of Pt->B Bonding in Oxidative Addition Reactions of the Platinaboratrane [Pt(PPh3){B(mt)3}](Pt¿B)10 (mt = Methimazolyl). Organometallics, 27 (3). pp. 312-315. ISSN 0276-7333

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Abstract

The platinaboratrane [Pt(PPh3){B(mt)3}](PtB)10 (mt = methimazolyl) is prone to oxidative addition reactions with a range of substrates (Cl2, Br2, I2, HCl, CH3I) without disrupting the platinum-boron dative bond, as illustrated by the first structurally characterized platinaboratranes [PtH(PPh3){B(mt)3}]Cl(PtB)8 and [PtI2{B(mt)3}](PtB)8.

Item Type:	Article
Additional Information:	Sole experimentalist, other authors = group PI (AFH) and crystallographer
Schools and Departments:	School of Life Sciences > Chemistry
Subjects:	Q Science
Depositing User:	Ian Crossley
Date Deposited:	06 Feb 2012 18:27
Last Modified:	03 Oct 2012 10:56
URI:	http://sro.sussex.ac.uk/id/eprint/16410

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