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Synthetic and structural studies on amine coordination to Pd-N-heterocyclic carbene complexes
journal contribution
posted on 2023-06-07, 19:27 authored by Alexandra k de k Lewis, Stephen Caddick, Oriana Esposito, Geoff Cloke, Peter B HitchcockThe reaction between 2-chlorobenzylamine or 2-chlorobenzylalcohol and Pd((IBu)-Bu-t)(2) ((IBu)-Bu-t = 1,3-di-tert-butylimidazol-2-ylidene) in benzene affords the dimeric complexes [Pd((IBu)-Bu-t)(mu-NH{2-CH2C6H4})](2) and [Pd((IBu)-Bu-t)(mu-O{2-CH2C6H4})](2); the latter has been structurally characterised. The syntheses, structural characterisation and reactivity of the Pd-NHC amine complexes [(ItBu)Pd(R-4-C6H4)(morpholine)Cl] (R = Me, OMe, CO2Me), intermediates in the Buchwald-Hartwig aryl amination reaction, are also reported.
History
Publication status
- Published
Journal
Dalton TransactionsISSN
1477-9226Publisher
Royal Society of ChemistryExternal DOI
Volume
35Page range
7094-7098Department affiliated with
- Chemistry Publications
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- No
Peer reviewed?
- Yes
Legacy Posted Date
2012-02-06Usage metrics
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