acs.inorgchem.2c03737.pdf (5.12 MB)
Chiral Co3Y propeller-shaped chemosensory platforms based on 19F-NMR
journal contribution
posted on 2023-06-10, 06:00 authored by Gabrielle Audsley, Harry Carpenter, Nsikak Essien, James Lai-MorriceJames Lai-Morrice, Youssra Al-Hilaly, Louise SerpellLouise Serpell, Geoffrey R Akien, Graham J Tizzard, Simon J Coles, Cristina Pubill Ulldemolins, George KostakisGeorge KostakisTwo propeller-shaped chiral CoIII3YIII complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-Ray diffraction (SXRD), IR, UV-Vis, Circular Dichroism (CD), Elemental analysis, Thermogravimetric analysis (TGA), Electron Spray Ionization Mass Spectroscopy (ESI-MS) and NMR (1H, 13C and 19F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a 19F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented.
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Publication status
- Published
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- Published version
Journal
Inorganic Chemistry: including bioinorganic chemistryISSN
0020-1669Publisher
American Chemical SocietyExternal DOI
Issue
6Volume
62Page range
2680-2693Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2023-01-17First Open Access (FOA) Date
2023-02-22First Compliant Deposit (FCD) Date
2023-01-17Usage metrics
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