File(s) under permanent embargo
Reversible structural isomerisation in rare thioether complexes of cobalt(ii) - effects of ligand architecture
journal contribution
posted on 2023-06-10, 01:35 authored by John Evans, William Levason, Joanna M Manning, Gillian Reid, Nikolaos Tsoureas, Michael WebsterRare examples of (high spin) Co(ii) complexes with geometrically constrained tetrathioether ligands exhibit a very unusual structural isomerism, switching reversibly between tetrahedral monomers in solution and octahedral chain polymers in the solid; the crystal structures of one polymeric species and a tetrahedral monomer model compound are described.
History
Publication status
- Published
File Version
- Published version
Journal
Dalton TransactionsISSN
1477-9226Publisher
Royal Society of ChemistryExternal DOI
Issue
20Volume
2007Page range
1986-1988Event location
EnglandDepartment affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2021-11-01First Compliant Deposit (FCD) Date
2021-10-30Usage metrics
Categories
No categories selectedKeywords
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC