Reversible structural isomerisation in rare thioether complexes of cobalt(ii) - effects of ligand architecture

Evans, John, Levason, William, Manning, Joanna M, Reid, Gillian, Tsoureas, Nikolaos and Webster, Michael (2007) Reversible structural isomerisation in rare thioether complexes of cobalt(ii) - effects of ligand architecture. Dalton Transactions, 2007 (20). pp. 1986-1988. ISSN 1477-9226

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Abstract

Rare examples of (high spin) Co(ii) complexes with geometrically constrained tetrathioether ligands exhibit a very unusual structural isomerism, switching reversibly between tetrahedral monomers in solution and octahedral chain polymers in the solid; the crystal structures of one polymeric species and a tetrahedral monomer model compound are described.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
SWORD Depositor: Mx Elements Account
Depositing User: Mx Elements Account
Date Deposited: 01 Nov 2021 10:35
Last Modified: 01 Nov 2021 10:45
URI: http://sro.sussex.ac.uk/id/eprint/102586

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