N-heterocyclic pincer dicarbene complexes of iron(II): C-2 and C-5 metalated carbenes on the same metal center

Danopoulos, Andreas A, Tsoureas, Nikolaos, Wright, Joseph A and Light, Mark E (2004) N-heterocyclic pincer dicarbene complexes of iron(II): C-2 and C-5 metalated carbenes on the same metal center. Organometallics, 23 (2). pp. 166-168. ISSN 0276-7333

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Abstract

Six- and five-coordinate Fe(II) complexes with the pincer Iigand 2,6-bis(imidazolylidene)pyridine (C-N-C), [(C-N-C)Fe(MeCN)3][BPh 4]2 and [(C-N-C)FeBr2], respectively, were synthesized. Substitution of tmeda in [FeCl2(tmeda)]2 by C-N-C gave the sixcoordinate {[Fe(C-N-C)(C-N-C*)][FeCl4]}, in which one of the pincer ligands is bound to the metal via the 2- and 5-imidazole carbons.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
SWORD Depositor: Mx Elements Account
Depositing User: Mx Elements Account
Date Deposited: 01 Nov 2021 10:20
Last Modified: 01 Nov 2021 10:20
URI: http://sro.sussex.ac.uk/id/eprint/102584

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