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N-heterocyclic pincer dicarbene complexes of iron(II): C-2 and C-5 metalated carbenes on the same metal center
journal contribution
posted on 2023-06-10, 01:35 authored by Andreas A Danopoulos, Nikolaos Tsoureas, Joseph A Wright, Mark E LightSix- and five-coordinate Fe(II) complexes with the pincer Iigand 2,6-bis(imidazolylidene)pyridine (C-N-C), [(C-N-C)Fe(MeCN)3][BPh 4]2 and [(C-N-C)FeBr2], respectively, were synthesized. Substitution of tmeda in [FeCl2(tmeda)]2 by C-N-C gave the sixcoordinate {[Fe(C-N-C)(C-N-C*)][FeCl4]}, in which one of the pincer ligands is bound to the metal via the 2- and 5-imidazole carbons.
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Publication status
- Published
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- Published version
Journal
OrganometallicsISSN
0276-7333Publisher
American Chemical SocietyExternal DOI
Issue
2Volume
23Page range
166-168Department affiliated with
- Chemistry Publications
Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2021-11-01First Compliant Deposit (FCD) Date
2021-10-30Usage metrics
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