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The first example of the two-electron reduction of a phosphaalkyne - Synthesis and structural characterisation of the diuranium(IV) pentalene complex [(U{?5-C5Me5}{?8-C 8H4(SiiPr3-1,4)2}) 2(µ-?2:?1-tBuCP)]
journal contribution
posted on 2023-06-10, 01:34 authored by Nikolaos Tsoureas, Alexander F R Kilpatrick, Owen T Summerscales, John F Nixon, Geoff Cloke, Peter B HitchcockThe facile two-electron reduction of the phosphaalkyne tBuC=P by the U III cyclopentadienyl-pentalene mixed-sandwich complex [U(?5-C5Me5){?8-C 8H4(SiiPr3)2}] is reported. A single-crystal X-ray structural analysis of the diuranium(IV) product [(U{?5-C5Me5}{?8-C 8H4(SiiPr3)2})2(µ- tBuCP)] shows that it contains a slightly unsymmetrical, bridging µ-?2:?1- ligated phosphaalkene dianion.
History
Publication status
- Published
File Version
- Published version
Journal
European Journal of Inorganic ChemistryISSN
1434-1948Publisher
WileyExternal DOI
Issue
22-23Volume
2013Page range
4085-4089Department affiliated with
- Chemistry Publications
Notes
Special Issue: small-molecule activation by reactive metal complexes (Cluster Issue)Full text available
- No
Peer reviewed?
- Yes
Legacy Posted Date
2021-11-01First Compliant Deposit (FCD) Date
2021-10-30Usage metrics
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