Sussex Research Online: No conditions. Results ordered -Date Deposited. 2023-11-14T07:21:28Z EPrints https://sro.sussex.ac.uk/images/sitelogo.png http://sro.sussex.ac.uk/ 2012-02-06T20:50:29Z 2012-03-28T13:36:14Z http://sro.sussex.ac.uk/id/eprint/28406 This item is in the repository with the URL: http://sro.sussex.ac.uk/id/eprint/28406 2012-02-06T20:50:29Z The sulfinyl moiety in Lewis base-promoted allylations

By employing Senanayake's oxathiazolidine-2-oxide reagent, a collection of sulfinamides was prepared and provided the first examples of sulfinamides promoting the allylation of benzaldehyde and N-benzoylhydrazones with allyltrichlorosilane. The optimum sulfinamide-derived Lewis base promoter displays comparable activity to the best sulfinyl-based Lewis bases reported. The use of bis-sulfoxides is also discussed.

 J Robin Fulton 155840 Lamin M Kamara 169356 Simon C Morton Gareth J Rowlands 109035 2012-02-06T18:29:12Z 2012-06-12T12:18:02Z http://sro.sussex.ac.uk/id/eprint/16667 This item is in the repository with the URL: http://sro.sussex.ac.uk/id/eprint/16667 2012-02-06T18:29:12Z Facile synthesis of planar chiral N-oxides and their use in Lewis base catalysis

A rapid and versatile method for the preparation of planar chiral [2.2]paracyclophane-derived pyridines and pyridine N-oxides is reported. The potential utility of these compounds in Lewis base catalysis is briefly introduced

 J R Fulton 155840 J E Glover L Kamara 169356 G J Rowlands 109035