University of Sussex
Browse
__smbhome.uscs.susx.ac.uk_ai216_Desktop_Pal_et_al-2016-Angewandte_Chemie_International_Edition.pdf (1.05 MB)

Iron- and cobalt-catalyzed synthesis of carbene phosphinidenes

Download (1.05 MB)
journal contribution
posted on 2023-06-09, 13:03 authored by Kuntal Pal, Oliver B Hemming, Benjamin M Day, Thomas Pugh, David J Evans, Richard LayfieldRichard Layfield
In the presence of stoichiometric or catalytic amounts of [M{N(SiMe3)2}2] (M=Fe, Co), N-heterocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of the type (NHC)·PAr. The formation of (IMe4)·PMes (Mes=mesityl) is also catalysed by the phosphinidene-bridged complex [(IMe4)2Fe-(m-PMes)]2, which provides evidence for metal-catalysed phosphinidene transfer.

History

Publication status

  • Published

File Version

  • Published version

Journal

Angewandte Chemie International Edition

ISSN

1433-7851

Publisher

Wiley

Issue

5

Volume

55

Page range

1690-1693

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2018-09-07

First Open Access (FOA) Date

2018-09-07

First Compliant Deposit (FCD) Date

2018-09-07

Usage metrics

    University of Sussex (Publications)

    Categories

    No categories selected

    Licence

    Exports

    RefWorks
    BibTeX
    Ref. manager
    Endnote
    DataCite
    NLM
    DC