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Through-conjugation of two phosphaalkyne (‘CP’) moieties mediated by a bimetallic scaffold†
Version 2 2023-06-12, 08:50
Version 1 2023-06-09, 12:25
journal contribution
posted on 2023-06-12, 08:50 authored by Matthew C Leech, Ian CrossleyIan CrossleyThrough-conjugation of two phosphaalkyne moieties within an isolable molecule is demonstrated for the first time with the synthesis of [{Ru(dppe)2}2{µ-(CC)2C6H4-p}(CP)2], via base induced desilylation of [{Ru(dppe)2}2{µ-(CC)2C6H4 p}Cl2]. The nature of the cyaphide ligands and their influence upon the bimetallic core are studied electrochemically.
Funding
Polymetallaphosphacarbons: Toward phosphorus-doped organometallic molecular wires; G1182; ROYAL SOCIETY; UF120021
Linearly Conjugated Phosphacarbon Organometallics; G1810; EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCIL; EP/N016785/1
History
Publication status
- Published
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- Published version
Journal
Dalton TransactionsISSN
1477-9226Publisher
Royal Society of ChemistryExternal DOI
Volume
47Page range
4428-4432Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2018-03-08First Open Access (FOA) Date
2018-03-28First Compliant Deposit (FCD) Date
2018-03-08Usage metrics
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