Through-conjugation of two phosphaalkyne (‘CP’) moieties mediated by a bimetallic scaffold†

Leech, Matthew C and Crossley, Ian R (2018) Through-conjugation of two phosphaalkyne (‘CP’) moieties mediated by a bimetallic scaffold†. Dalton Transactions, 47. pp. 4428-4432. ISSN 1477-9226

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Abstract

Through-conjugation of two phosphaalkyne moieties within an
isolable molecule is demonstrated for the first time with the synthesis of [{Ru(dppe)2}2{μ-(CC)2C6H4-p}(CP)2], via base induced desilylation of [{Ru(dppe)2}2{μ-(CC)2C6H4 p}Cl2]. The nature of the cyaphide ligands and their influence upon the bimetallic core are studied electrochemically.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry > QD0146 Inorganic chemistry
Related URLs:
Depositing User: Ian Crossley
Date Deposited: 08 Mar 2018 13:55
Last Modified: 28 Mar 2018 15:24
URI: http://sro.sussex.ac.uk/id/eprint/74320

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Project NameSussex Project NumberFunderFunder Ref
Polymetallaphosphacarbons: Toward phosphorus-doped organometallic molecular wiresG1182ROYAL SOCIETYUF120021
Linearly Conjugated Phosphacarbon OrganometallicsG1810EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCILEP/N016785/1