An undecanuclear ferrimagnetic Cu9Dy2 SMM achieved through ligand fine-tuning

Kühne, Irina A, Kostakis, George, Anson, Christopher E and Powell, Annie K (2016) An undecanuclear ferrimagnetic Cu9Dy2 SMM achieved through ligand fine-tuning. Inorganic Chemistry, 55 (9). pp. 4072-4074. ISSN 0020-1669

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Abstract

We describe the concept of increasing the nuclearity of a previously reported high-spin Cu5Gd2 core using a “fine tuning” ligand approach. Thus two Cu9Ln2 coordination clusters, with Ln = Dy (1), Gd(2) were synthesized with the Gd compound having a ground spin state of 17/2 and the Dy analogue showing SMM behavior in zero field.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry > QD0146 Inorganic chemistry
Depositing User: Georgios Kostakis
Date Deposited: 23 Nov 2017 14:21
Last Modified: 14 Dec 2017 10:04
URI: http://sro.sussex.ac.uk/id/eprint/71521

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