Heptanuclear disk-like MII3LnIII4 (M=Ni, Co) coordination clusters: synthesis, structures and magnetic properties

Griffiths, Kieran, Harding, Chris, Dokorou, Vasiliki N, Loukopoulos, Edward, Sampani, Stavroula I, Abdul-Sada, Alaa, Tizzard, Graham J, Coles, Simon J, Lorusso, Giulia, Evangelisti, Marco, Escuer, Albert and Kostakis, George E (2017) Heptanuclear disk-like MII3LnIII4 (M=Ni, Co) coordination clusters: synthesis, structures and magnetic properties. European Journal of Inorganic Chemistry. ISSN 1434-1948 (Accepted)

[img] PDF (This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving) - Accepted Version
Restricted to SRO admin only

Download (880kB)

Abstract

The synthesis, characterization, crystal structures and magnetic properties of isoskeletal heptanuclear disk-like MII 3LnIII 4 coordination clusters with the general formula [CoII 3LnIII 4(µ3- OH)6L6(CF3SO3)](CF3SO3)5] where Ln= Gd (2), Y (3) and [NiII 3LnIII 4(µ3- OH)6L6(CF3SO3)](CF3SO3)5] where Ln= Dy (4), Gd (5), Y (6) are presented. All the compounds are stable in solution as confirmed by ESI-MS. Magnetic studies were performed for compounds 2, 4, 5 and 6 and indicate ferromagnetic coupling while the magnetocaloric properties of 5 are characterized by ΔSm = -15.4 Jkg-1K -1 at T = 5.0 K and Tad = 5.9 K at T = 2.3 K, for µ0ΔH = 7 T.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry > QD0146 Inorganic chemistry
Depositing User: Georgios Kostakis
Date Deposited: 25 Jul 2017 16:38
Last Modified: 25 Jul 2017 17:33
URI: http://sro.sussex.ac.uk/id/eprint/69436

View download statistics for this item

📧 Request an update