Loukopoulos, Edward, Kallitsakis, Michael, Tsoureas, Nikolaos, Abdul-Sada, Alaa, Chilton, Nicholas F, Lykakis, Ioannis N and Kostakis, George N (2017) Cu(II) coordination polymers as vehicles in the A³ coupling. Inorganic Chemistry, 56 (9). pp. 4898-4910. ISSN 0020-1669
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Abstract
A family of benzotriazole based coordination compounds, obtained in two steps and good yields from commercially available materials, formulated [CuII(L 1 )2(MeCN)2]·2(ClO4)·MeCN (1), [CuII(L 1 )(NO3)2]·MeCN (2), [ZnII(L 1 )2(H2O)2]·2(ClO4)·2MeCN (3), [CuII (L 1 )2Cl2]2 (4), [CuII 5(L 1 )2Cl10] (5), [CuII 2(L 1 )4Br2]·4MeCN·(CuII 2Br6) (6), [CuII(L 1 )2(MeCN)2]·2(BF4) (7), [CuII(L 1 )2(CF3SO3)2] (8), [ZnII(L 1 )2(MeCN)2]·2(CF3SO3) (9), [CuII 2(L 2 )4(H2O)2]·4(CF3SO3)·4Me2CO (10) and [CuII 2(L 3 )4(CF3SO3)2]·2(CF3SO3)·Me2CO (11) are reported. These air stable compounds were tested as homogeneous catalysts for the A3 coupling synthesis of propargyl amine derivatives from aldehyde, amine and alkyne under a non-inert atmosphere. Fine-tuning of the catalyst resulted in a one dimensional (1D) coordination polymer (CP) (8) with excellent catalytic activity in a wide range of substrates, avoiding any issues that would inhibit its performance.
Item Type: | Article |
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Schools and Departments: | School of Life Sciences > Chemistry |
Subjects: | Q Science > QD Chemistry > QD0146 Inorganic chemistry |
Depositing User: | Georgios Kostakis |
Date Deposited: | 31 Mar 2017 11:52 |
Last Modified: | 11 Apr 2018 01:00 |
URI: | http://sro.sussex.ac.uk/id/eprint/67234 |
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