Five Mononuclear pentacoordinate Co(II) complexes with field induced slow magnetic relaxation.pdf (1.3 MB)
Five mononuclear pentacoordinate Co(II) complexes with field-induced slow magnetic relaxation
journal contribution
posted on 2023-06-09, 05:12 authored by Cyril Rajnák, Ján Titiš, Jozef Miklovic, George KostakisGeorge Kostakis, Olaf Fuhr, Mario Ruben, Roman BocaFive related mononuclear pentacoordinate complexes of the formula [CoL³Cl2] show slow magnetic relaxation under small applied DC field; L³ – a tridentate N-donor ligand based upon dipyrazolpyridine with an alkyl tail. All of them exhibit a supramolecular assembly, either forming dimers or chains via p–p stacking. Moreover, they display two relaxation branches, one being typical for single molecule magnets of this class, t ~ 10-6 s, and the second one as slow as t ~ 0.5 s at T = 1.9 K.
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Publication status
- Published
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- Accepted version
Journal
PolyhedronISSN
0277-5387Publisher
ElsevierExternal DOI
Volume
126Page range
174-183Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2017-02-16First Open Access (FOA) Date
2018-01-29First Compliant Deposit (FCD) Date
2017-02-21Usage metrics
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