Transition metal catalyzed element–element′ additions to alkynes

Ansell, Melvyn B, Navarro, Oscar and Spencer, John (2017) Transition metal catalyzed element–element′ additions to alkynes. Coordination Chemistry Reviews, 336. pp. 54-77. ISSN 0010-8545

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Abstract

The efficient and stereoselective synthesis of, or precursors to, multi-substituted alkenes has attracted substantial interest due to their existence in various industrially and biologically important compounds. One of the most atom economical routes to such alkenes is the transition metal catalyzed hetero element–element′ π-insertion into alkynes. This article provides a thorough up-to-date review on this area of chemistry, including discussions on the mechanism, range of Esingle bondE′ bonds accessible and the stoichiometric/catalytic transition metal mediators employed.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry > QD0146 Inorganic chemistry
Q Science > QD Chemistry > QD0241 Organic chemistry
Depositing User: John Spencer
Date Deposited: 31 Jan 2017 09:50
Last Modified: 12 Sep 2017 15:54
URI: http://sro.sussex.ac.uk/id/eprint/66514

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Project NameSussex Project NumberFunderFunder Ref
DTA - University of Sussex 2013 (EPSRC)G1142EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCILEP/L505109/1