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A base-free synthetic route to anti-bimetallic lanthanide pentalene complexes

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posted on 2023-06-09, 04:32 authored by Alexander F R Kilpatrick, Geoff Cloke
We report the synthesis and structural characterisation of three homobimetallic complexes featuring divalent lanthanide metals (Ln = Yb, Eu and Sm) bridged by the silylated pentalene ligand [1,4-{SiiPr3}2C8H4]2- (= Pn†). Magnetic measurements and cyclic voltammetry have been used to investigate the extent of intermetallic communication in these systems, in the context of molecular models for organolanthanide based conducting materials.

History

Publication status

  • Published

File Version

  • Accepted version

Journal

Dalton Transactions

ISSN

1477-9226

Publisher

Royal Society of Chemistry

Issue

17

Volume

46

Page range

5587-5597

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2017-01-04

First Open Access (FOA) Date

2017-12-23

First Compliant Deposit (FCD) Date

2017-01-04

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