Topological insights in polynuclear Ni/Na coordination clusters derived from a schiff base ligand

Griffiths, Kieran, Escuer, Albert and Kostakis, Georgios E (2016) Topological insights in polynuclear Ni/Na coordination clusters derived from a schiff base ligand. Structural Chemistry. ISSN 1040-0400

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Abstract

This article presents the syntheses, crystal structures, topological features and magnetic properties of two NiII/NaI coordination clusters (CCs) formulated [NiII3Na(L1)3(HL1 (MeOH)2] (1) and [NiII6Na(L1)5(CO3)(MeO (MeOH)3(H2O)3]·4(MeOH) 2(H2O) [2 4(MeOH) 2(H2O)] where H2L1 is the semi rigid Schiff base ligand (E)-2-(2-hydroxy-3 methoxybenzylideneamino)-phenol). Compound 1 possesses a rare NiII3NaI cubane (3M4-1) topology and compound 2 is the first example in polynuclear Ni/Na chemistry that exhibits a 2,3,4M7-1 topology.

Item Type: Article
Keywords: Coordination cluster, Nickel, Sodium, Topology, Schiff base, Ferromagnetism, Carbonate ion.
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry > QD0146 Inorganic chemistry
Depositing User: Georgios Kostakis
Date Deposited: 12 Oct 2016 12:48
Last Modified: 15 Aug 2017 11:21
URI: http://sro.sussex.ac.uk/id/eprint/62373

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