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Topological insights in polynuclear Ni/Na coordination clusters derived from a schiff base ligand

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journal contribution
posted on 2023-06-12, 06:43 authored by Kieran Griffiths, Albert Escuer, Georgios E Kostakis
This article presents the syntheses, crystal structures, topological features and magnetic properties of two NiII/NaI coordination clusters (CCs) formulated [NiII3Na(L1)3(HL1 (MeOH)2] (1) and [NiII6Na(L1)5(CO3)(MeO (MeOH)3(H2O)3]·4(MeOH) 2(H2O) [2 4(MeOH) 2(H2O)] where H2L1 is the semi rigid Schiff base ligand (E)-2-(2-hydroxy-3 methoxybenzylideneamino)-phenol). Compound 1 possesses a rare NiII3NaI cubane (3M4-1) topology and compound 2 is the first example in polynuclear Ni/Na chemistry that exhibits a 2,3,4M7-1 topology.

History

Publication status

  • Published

File Version

  • Published version

Journal

Structural Chemistry

ISSN

1040-0400

Publisher

Springer Verlag

Issue

6

Volume

27

Page range

1703-1714

Department affiliated with

  • Chemistry Publications

Full text available

  • Yes

Peer reviewed?

  • Yes

Legacy Posted Date

2016-10-12

First Open Access (FOA) Date

2017-08-09

First Compliant Deposit (FCD) Date

2016-10-12

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