Griffiths2016_Article_TopologicalInsightsInPolynucle.pdf (1.11 MB)
Topological insights in polynuclear Ni/Na coordination clusters derived from a schiff base ligand
Version 2 2023-06-12, 06:43
Version 1 2023-06-09, 02:31
journal contribution
posted on 2023-06-12, 06:43 authored by Kieran Griffiths, Albert Escuer, Georgios E KostakisThis article presents the syntheses, crystal structures, topological features and magnetic properties of two NiII/NaI coordination clusters (CCs) formulated [NiII3Na(L1)3(HL1 (MeOH)2] (1) and [NiII6Na(L1)5(CO3)(MeO (MeOH)3(H2O)3]·4(MeOH) 2(H2O) [2 4(MeOH) 2(H2O)] where H2L1 is the semi rigid Schiff base ligand (E)-2-(2-hydroxy-3 methoxybenzylideneamino)-phenol). Compound 1 possesses a rare NiII3NaI cubane (3M4-1) topology and compound 2 is the first example in polynuclear Ni/Na chemistry that exhibits a 2,3,4M7-1 topology.
History
Publication status
- Published
File Version
- Published version
Journal
Structural ChemistryISSN
1040-0400Publisher
Springer VerlagExternal DOI
Issue
6Volume
27Page range
1703-1714Department affiliated with
- Chemistry Publications
Full text available
- Yes
Peer reviewed?
- Yes