Tetranuclear Zn2Ln2 coordination clusters as catalysts in Petasis borono-Mannich multicomponent reaction

Kumar, Prashant, Griffiths, Kieran, Lymperopoulou, Smaragda and Kostakis, George E (2016) Tetranuclear Zn2Ln2 coordination clusters as catalysts in Petasis borono-Mannich multicomponent reaction. RSC Advances, 6 (82). pp. 79180-79184. ISSN 2046-2069

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Abstract

We report herein for the first time the efficiency of heteronuclear Zn/Ln coordination clusters (CCs) as catalysts for the multicomponent Mannich-type condensation that involves amines, aldehydes and boronic acids, known as Petasis borono-Mannich (RBR) reaction. The reaction proceeds in very good to excellent yields (84-98%, 17 products) at room temperature with catalyst loadings as low as 1.0 mol%.

Item Type: Article
Schools and Departments: School of Life Sciences > Chemistry
Subjects: Q Science > QD Chemistry > QD0146 Inorganic chemistry
Depositing User: Georgios Kostakis
Date Deposited: 11 Aug 2016 10:02
Last Modified: 15 Aug 2017 11:21
URI: http://sro.sussex.ac.uk/id/eprint/62364

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Project NameSussex Project NumberFunderFunder Ref
Defect dicubane 3d/Dy(III) Coordination Clusters: Heading for materials displaying catalytic propertiesG1632EPSRC-ENGINEERING & PHYSICAL SCIENCES RESEARCH COUNCILEP/M023834/1