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Tetranuclear Zn/4f coordination clusters as highly efficient catalysts for Friedel-Crafts alkylation
Version 2 2023-06-12, 06:40
Version 1 2023-06-09, 01:41
journal contribution
posted on 2023-06-12, 06:40 authored by Kieran Griffiths, Prashant Kumar, Geoffrey R Akien, Nicholas F Chilton, Alaa Abdul-Sada, Graham J Tizzard, Simon J Coles, George KostakisGeorge KostakisA series of custom-designed, high yield, isoskeletal tetranuclear Zn/4f coordination clusters showing high efficiency as catalysts with low catalytic loadings in Friedel-Crafts alkylation are described for the first time. The possibility of altering the 4f centers in these catalysts without altering the core topology allows us to further confirm their stability via EPR and NMR, as well to gain insights into the plausible reaction mechanism, showcasing the usefulness of these bimetallic systems as catalysts.
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Publication status
- Published
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- Published version
Journal
Chemical CommunicationsISSN
1359-7345Publisher
Royal Society of ChemistryExternal DOI
Issue
50Volume
52Page range
7866-7869Department affiliated with
- Chemistry Publications
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- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2016-06-15First Open Access (FOA) Date
2016-07-07First Compliant Deposit (FCD) Date
2016-06-15Usage metrics
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