Bra-Gar-Pal-MMS-revised.pdf (1.38 MB)
Interfacial energies of systems of chiral molecules
journal contribution
posted on 2023-06-09, 01:10 authored by Andrea Braides, Andrea Garroni, Mariapia PalombaroWe consider a simple model for the assembly of chiral molecules in two dimensions driven by maximization of the contact area. We derive a macroscopic model described by a parameter taking nine possible values corresponding to the possible minimal microscopic patterns and modulated phases of the chiral molecules. We describe the overall behaviour by means of an interaction energy of perimeter type between such phases. This energy is a crystalline perimeter energy, highlighting preferred directions for the interfaces between ensembles of molecules labelled by different values of the parameter.
History
Publication status
- Published
File Version
- Accepted version
Journal
Multiscale Modeling and Simulation: A SIAM Interdisciplinary JournalISSN
1540-3459Publisher
SIAMExternal DOI
Issue
3Volume
14Page range
1037-1062Department affiliated with
- Mathematics Publications
Full text available
- Yes
Peer reviewed?
- Yes
Legacy Posted Date
2016-05-09First Open Access (FOA) Date
2016-05-09First Compliant Deposit (FCD) Date
2016-05-09Usage metrics
Categories
No categories selectedKeywords
Licence
Exports
RefWorks
BibTeX
Ref. manager
Endnote
DataCite
NLM
DC